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    • 智能高分子材料的微结构修饰(英文版)
      • 作者:编者:冯传良//窦晓秋//徐亦斌|责编:杨迎春
      • 出版社:上海交大
      • ISBN:9787313220998
      • 出版日期:2021/11/01
      • 页数:183
    • 售价:19.6
  • 内容大纲

        本书从基本方法和原理出发,论述了高分子微结构修饰调控材料表界面性能的先进技术与设计。主要内容包括高分子微结构修饰方法如自组装单分子层法、微区接触反应法、平板印刷法等,及其在生物学领域中的巨大应用前景如诱导细胞定向生长、生物分子检测、肿瘤细胞灵敏抓捕等。本书可供高分子材料领域研究人员,以及从事材料表界面设计的料研工作者和相关研究生参考。
  • 作者介绍

  • 目录

    Chapter 1 Reactive Platforms for Controllable Fabrication of Functional
      (Bio)Interfaces
      1.1  Scope of Surface Modification for (Bio)Reactive Platfor ms
      and Functional (Bio)Interfaces
      1.2  Chemical and Topographical Pattern Fabrication
      from Micrometer to Nanometer Length Scales
      References
    Chapter 2 Surface Reactions and Fabrication of Bioreactive Platforms
      Based on Organic and Polymeric Films: From Micrometer
      to Nanometer Length Scale
      2.1  Introduction: Bioreactive Platforms and Biointerfaces
      via Organic and Polymeric Films
        2.1.1  Organic and Polymeric Films
        2.1.2  Pattern Fabrication on Organic and Polymeric Films
      2.2  Surface Reactions of Organic and Polymeric Films
        2.2.1  Self-assembled Monolayers
        2.2.2  Surface Modification with Polymers
      2.3  Patterned Organic and Polymeric Films for Tailored
      (Bio)Interfaces
        2.3.1  Microcontact Printing
        2.3.2  Selective Molecular Assembly Patterning (SMAP)
        2.3.3  Embossing and Nano-Imprinting
        2.3.4  Self-assembled Block Copoly mer Patterns
      References
    Chapter 3 Confinement Effects on the Reactivity in Ultrathin Polymer
      Films: Kinetics and Temperature Dependence of the Hydrolysis
      of NHS and TBA Esters
      3.1  Introduction
      3.2  Ultrathin PNHSMA Polymer Films
        3.2.1  Characterization of the Hydrolysis of PNHSMA Films
        3.2.2  Temperature Dependence of Reaction Kinetics
        3.2.3  Comparison of Surface Reactions in SAMs
      and Ultrathin Polymer Films
      3.3  Ultrathin PS_-b-PiBA_ Polvmer Films
        3.3.1  Characterization of Polymer Thin Film Surface
      Composition
        3.3.2  Characterization and Kinetics of the Hydrolysis
      of PSm-b-PtBA, Films
        3.3.3  Investigation of the Temperature Dependence
      of Reaction Kinetics
        3.3.4  Effects of Film Thickness and Thermal Pretreatment
      on Reaction Rates
        3.3.5  Dependence of Hydrolysis Kinetics on Surface
      Composition
        3.3.6  Comparison of Reactivity of T-Butyl Esters
      in PS,-b-PtBAm Thin Films and in Solution
      3.4  Experimental Section
      References
    Chapter 4 Reactive Thin Polymer Films as Platfor ms
      for the Immobilization of Biomolecules

      4.1  Introduction
      4.2  Investigation of the Reactivity of PNHS MA
        4.2.1  Coupling of PEGsoo-NH2
        4.2.2  Coupling of Fluoresceinamine and BSA to PNHSMA
      Films1wvve
        4.2.3  Comparison of Surface Reactions on PNHSMA Films
      and NHS-C10 Monolayers
      4.3  Swelling Behavior and Stability of PNHSMA Films
      4.4  Immobilization of DNA and Surface-Based Hybridization
        4.4.1  DNA Immobilization Studied by SPR
        4.4.2  Investigation of DNA Hybridization by SPFS
      and Fluorescence Microscopy
      4.5  Toward the Detection of Pathogenic Bacteria on PNHSMA
      Films
      4.6  Experimental Section
      References
    Chapter 5 Tailored Biointerfaces via Derivatization
      of Polystyrene-b-Poly(Tert-Butyl Acrylate) Thin Films
      5.1  Introduction
      5.2  Investigation of the Surface Chemistry of PS690-b-PtBA1210
      Films
        5.2.1  Surface Hydrolysis of PS690-b-PtBA1210 Films
        5.2.2  Covalent Coupling of PEG to Activated
      PSkon-b-PtBA n Films
      5.3  Covalent Coupling of Biomolecules to Activated
      PS690-b-PtBA1210 Films
      5.4  Cell Adhesion Studies on PSs90-b-PtBA1210 Films
      5.5  Experimental Section
      References
    Chapter 6 Fabrication of Robust Biomolecular Patterns by Reactive
      Microcontact Printing on NHS Ester Containing Polymer Films
      6.1  Introduction
      6.2  Approaches for Micropatterning of PNHSMA Films
      6.3  Functionalization of PNHSMA Films by Reactive u.CP
      6.4  Non-specific Adsorption (NSA)
      6.5  Patterning of PNHSMA and Coupling of (Bio)Molecules
      to Patterned Films
      6.6  DNA Hybridization
      6.7  Experimental Section
      References
    Chapter 7 Reactive uCP on Ultrathin Block Copolymer Films
      Investigation of the uCP Mechanism and Applications
      to Sub-um (Bio)Molecular Patterning
      7.1  Introduction
      7.2  Strategy A: Fabrication of Multimolecular Arrays by Direct
      Molecular Transfer
      7.3  Strategy B: Local Passivation of PS690-b-PtBA1210 Films
      7.4  Strategy C: Local Deprotection of PS90-b-PtBA1210 Films
        7.4.1  Analysis by Fluorescence Microscopy
        7.4.2  Analysis by AFM

        7.4.3  Mechanism of Local Hydrolysis
        7.4.4  Local Deprotection on the Sub-um Scale
      7.5  Experimental Section
      References
    Chapter 8 Nanofabrication on Reactive Block Copolymer Film Platforms
      Toward Microdomain-Selective Chemical Functionalization
      8.1  Introduction
      8.2  Solvent-Induced Surface Reorientation of PS-b-PtBA Films
      8.3  Domain-Selective Coupling on Solvent-Treated Polymer
      Films
        8.3.1  Global Characterization of Domain-Selective
      Coupling
        8.3.2  Characterization of Do main-Selective Coupling
      at the Nanometer Level
      8.4  Area-Selective Functionalization of Block Copolymer-Based
      Nanopatterned Platforms
      8.5  Outlook
      8.6  Experimental Section
      References
    Chapter 9 Bioinspired Hierarchically Structured Poly mer Interfaces
      for Prornising Biomedical Applications
      9.1  Introduction
      9.2  Preparation of Rose Petal-Derived PDMS Surface
      Functionalized with Anti-EpCAM
        9.2.1  Fabrication of Hierarchically Structured PDMS
        9.2.2  Chemical Modification of Anti-EpCAM
      on Hierarchically Structured PDMS Surface
      9.3  Cell-Capture on Functionalized Hierarchical PDMS
        9.3.1  Cell-Capture
        9.3.2  Cell Release
      9.4  Conclusions and Outlook
      9.5  Experimental Section
    References

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