- 有机化学(英文版第2版普通高等教育石油和化工行业十四五规划教材)
- - 作者：编者:刘睿//朱红军|责编:宋林青
  - 出版社：化学工业
  - ISBN：9787122456397
  - 出版日期：2025/01/01
  - 页数：452
- 售价：31.2

内容大纲
《有机化学（英文版）》（第二版）共21章，分别为概论，烷烃，烯烃，共轭二烯烃，环烷烃，炔烃，立体化学，卤代烃，苯及芳香化学，醇、酚、醚，核磁共振波谱，红外光谱，醛和酮，羧酸及其衍生物，双官能团化合物，胺及其他含氮化合物，杂环化合物，碳水化合物，氨基酸、多肽、蛋白质和核酸，金属有机化合物，周环反应等内容。本书注重对各类化合物结构的介绍，以强化结构决定性质和反应这一有机化合物的基本特征。本书在编写时引入有机化学家事迹、化学史、学科前沿等内容，以增加学生的学习兴趣，提高科学素养。本书为英文写作，有助于提升学习者专业英语的阅读和理解能力，提升与国外高校和科研机构的合作与交流能力。本书采取双色印刷，对重点专业名词和官能团转化进行颜色区分，有利于掌握有机化学的基本规律。
《有机化学（英文版）》（第二版）可作为化学类、化工与制药类、材料类、药学类、食品科学与工程类、生物工程类、环境科学与工程类、轻化工程类等专业本科生及研究生的教材，也可作为有关研究院所和企业科研人员的参考书。
作者介绍
目录
Chapter 1  Introduction
  1.1  The Development of Organic Chemistry
  1.2  The Structural Theory of Organic Chemistry
    1.2.1  Atomic orbitals
    1.2.2  Ionic bonding
    1.2.3  Covalent bonding
    1.2.4  Hybridization
    1.2.5  Polar covalent bond, electronegativity and dipole moment
  1.3  Acid-Base Theory in Organic Chemistry
    1.3.1  Brnsted-Lowry acids and bases
    1.3.2  Lewis acids and bases
  1.4  Function Groups and Classify of Organic Chemical Compounds
  Extending reading: Linus Pauling
  Problems
Chapter 2  Alkanes
  2.1  Introduction
  2.2  Nomenclature of Alkanes
    2.2.1  Nomenclature of unbranched alkyl groups
    2.2.2  Nomenclature of branched-chain alkanes
    2.2.3  Nomenclature of branched alkyl groups
    2.2.4  Classification of hydrogen atoms
  2.3  Structure and Conformations of Alkanes
    2.3.1  Structure of methane
    2.3.2  Structure of ethane
    2.3.3  Free rotation, conformations, torsional strain of the carbon-carbon single bond
    2.3.4  Propane and the butane
    2.3.5  Conformations of n-butane: van der Waals repulsion
  2.4  Physical Properties of Alkanes
    2.4.1  Boiling point
    2.4.2  Melting point
    2.4.3  Solubility in water
  2.5  Chemical Properties of Alkanes
    2.5.1  Combustion of alkanes
    2.5.2  Pyrolysis of alkanes: Cracking
    2.5.3  Halogenation of alkanes
  2.6  Occurrence and Uses of Alkanes
    2.6.1  Sources of alkanes: petroleum
    2.6.2  Petroleum refining
    2.6.3  Cracking
  Extending reading: Jacobus Henricus van’t Hoff
  Problems
Chapter 3  Alkenes
  3.1  Structure of Alkenes
  3.2  Nomenclature and Geometric Isomerism of Alkenes
    3.2.1  Nomenclature of alkenes
    3.2.2  Geometric isomerism of alkenes and its nomenclature
  3.3  Physical Properties of Alkenes
  3.4  Preparation and Uses of Alkenes
    3.4.1  Dehydration
    3.4.2  Dehydrohalogenation

    3.4.3  Cracking
    3.4.4  Use of alkenes
  3.5  Chemical Properties of Alkenes
    3.5.1  Catalytic hydrogenation reaction
    3.5.2  Electrophilic addition to alkenes
    3.5.3  HBr free radical addition
    3.5.4  Addition of diboranes
    3.5.5  Reactions of alkenes with oxygen electrophiles
    3.5.6  The reaction of α-H
  3.6  Polymer and Plastics
  Extending reading: Synthesis of Palytoxin
  Problems
Chapter 4  Dienes and Conjugation
  4.1  Nomenclature of Dienes
  4.2  Structure and Stability of Conjugated Dienes
    4.2.1  Conjugative effect
    4.2.2  Molecular orbital (MO) of 1,3-butadiene
  4.3  Chemical Properties of Conjugative Dienes
    4.3.1  Electrophile addition
    4.3.2  Diels-Alder reaction
  4.4  Rubber
  Extending reading 1: Otto Paul Hermann Diels
  Extending reading 2: Kurt Alder
  Problems
Chapter 5  Cycloalkanes
  5.1  Nomenclature of Cycloalkanes
    5.1.1  Nomenclature of monocycloalkanes
    5.1.2  Nomenclature of polycycloalkanes
  5.2  Stabilities of Cycloalkanes
  5.3  Structures and Conformation of Cycloalkanes
    5.3.1  Structures and conformation of cyclopropane and cyclobutane
    5.3.2  Structures and conformation of cyclopentane
    5.3.3  Structures and conformation of cyclohexane
    5.3.4  Conformations of higher cycloalkanes
    5.3.5  Substituted cyclohexanes: axial and equatorial hydrogen atoms
  5.4  Chemical Properties of Cycloalkanes
  Extending reading: Derek Harold Richard Barton
  Problems
Chapter 6  Alkynes
  6.1  Structure of Alkynes
  6.2  Nomenclature of Alkynes
  6.3  Physical Properties of Alkynes
  6.4  Preparation and Uses of Alkynes
    6.4.1  Preparation of ethyne (HC≡CH)
    6.4.2  By elimination reaction
  6.5  Chemical Properties of Alkynes
    6.5.1  Acidity of terminal alkynes
    6.5.2  Addition by electrophilic reagents
    6.5.3  Hydroboration/oxidation of alkynes
    6.5.4  Reduction of alkynes

    6.5.5  Oxidation of alkynes
    6.5.6  Alkynes anions as nucleophiles
  Extending reading: Discovery of Acetylene
  Problems
Chapter 7  Stereochemistry
  7.1  Enantiomerism and Chirality
  7.2  Plane Polarized Light, Optical Activity and Specific Rotation
  7.3  Fischer Projection
  7.4  Configuration Representation Method, Configuration Labeling and Isomer Naming
    7.4.1  R/S absolute configuration representation
    7.4.2  D/L Relative configuration representation
  7.5  Diastereomers
  7.6  Resolution of Racemates
  Extending reading: The Critical Role of Stereochemistry in Organic Chemistry — Insights from the Thalidomide Tragedy
  Problems
Chapter 8  Alkyl Halides
  8.1  Classification and Nomenclature of Halogenated Hydrocarbons
  8.2  Structure of Halides
  8.3  Physical Properties of Halides
  8.4  Chemical Properties of Halogenated Hydrocarbons
    8.4.1  Nucleophilic substitution reaction
    8.4.2  Elimination reactions of alkyl halides
    8.4.3  Organometallic compounds and their reactions
  8.5  Reaction Mechanism and Influencing Factors of Nucleophilic Substitution Reaction
    8.5.1  The mechanism for SN2 reaction
    8.5.2  The mechanism for SN1 reaction
    8.5.3  Factors affecting the rates of SN1 and SN2 reactions
  8.6  Mechanisms of Dehydrohalogenation
    8.6.1  Bimolecular elimination reaction: E2 reaction
    8.6.2  Unimolecular elimination reaction: E1 reaction
  8.7  Substitution versus Elimination
    8.7.1  SN2 versus E
    8.7.2  Tertiary halides: SN1 versus E
  8.8  Halogenated Alkenes
    8.8.1  Vinyl halogenated alkenes
    8.8.2  Allyl halide alkenes
  8.9  Commonly Halogenated Hydrocarbons
  Extending reading: Paul Walden
  Problems
Chapter 9  Benzene and Aromatic Chemistry
  9.1  Structure of Benzene and Aromaticity
    9.1.1  Kekulé and the structure of benzene
    9.1.2  A resonance of bonding in benzene
    9.1.3  The stability of benzene
    9.1.4  The molecular orbitals of benzene
  9.2  Nomenclature of Benzene Derivatives
  9.3  Physical Properties of Benzene Derivatives
  9.4  Chemical Properties of Benzene Derivatives
    9.4.1  Reduction
    9.4.2  Oxidation of alkyl side-chains

    9.4.3  Free-radical halogenation of alkylbenzenes
  9.5  Electrophilic Aromatic Substitution Reactions of Substituted Benzenes
    9.5.1  Ortho, para-directing groups
    9.5.2  Meta-directing groups
  9.6  Polycyclic Aromatic Compounds
    9.6.1  Non-fused polycyclic aromatic hydrocarbons
    9.6.2  Fused polycyclic aromatic hydrocarbons
  9.7  Non-Benzene Aromatic Hydrocarbons
    9.7.1  Hückel rule
    9.7.2  Cyclobutadiene and cyclooctatetraene
    9.7.3  Annulene
    9.7.4  Cyclopentadiene and cycloheptatriene
  Extending reading: Discovery of Benzene and the Theory of Molecular Structure of Benzene
  Problems
Chapter 10  Alcohols, Phenols and Ethers
  10.1  Structure of Alcohols, Phenols and Ethers
    10.1.1  Structure of alcohols
    10.1.2  Structure of phenols
    10.1.3  Structure of ethers
  10.2  Nomenclature of Alcohols, Phenols and Ethers
    10.2.1  Nomenclature of alcohols
    10.2.2  Nomenclature of phenols
    10.2.3  Nomenclature of ethers
  10.3  Physical Properties of Alcohols, Phenols and Ethers
    10.3.1  Physical properties of alcohols
    10.3.2  Physical properties of phenols
    10.3.3  Physical properties of ethers
  10.4  Preparation and Uses of Alcohols
    10.4.1  Synthesis of alcohols by hydration of alkenes
    10.4.2  Synthesis of alcohols by addition to carbonyl groups
    10.4.3  Synthesis of alcohols by reduction of carbonyl-containing compounds
  10.5  Chemical Properties of Alcohols
    10.5.1  Acidity of alcohols
    10.5.2  Conversion to alkyl halides
    10.5.3  Dehydration of alcohols
    10.5.4  Esterification of alcohols
    10.5.5  Oxidation of alcohols
  10.6  Preparation and Uses of Phenols
    10.6.1  Laboratory synthesis
    10.6.2  Industrial synthesis
  10.7  Chemical Properties of Phenols
    10.7.1  Acidity of phenols
    10.7.2  Other reaction of the OH group of phenols
    10.7.3  Reaction of the benzene ring of phenols
  10.8  Preparation of Ethers
  10.9  Chemical Properties of Ethers
    10.9.1  The formation of oxonium salts
    10.9.2  Acid-catalyzed cleavage of ethers
    10.9.3  Autoxidation of ethers
  10.10  Thiols, Sulfides and Disulfides

  Extending reading: Victor Grignard
  Problems
Chapter 11  Nuclear Magnetic Resonance Spectroscopy
  11.1  Principles of Nuclear Magnetic Resonance
    11.1.1  Discovery of nuclear magnetic resonance
    11.1.2  Spin phenomenon of atomic nucleus
    11.1.3  The reasons of nuclear magnetic resonance
  11.2  Chemical Shift
    11.2.1  Definition of chemical shift
    11.2.2  Shielding effect
    11.2.3  Practical representation of chemical shift
    11.2.4  Factors affecting chemical shift
  11.3  Chemical Shifts of Characteristic Protons in 1H-NMR
  11.4  Integration Curves and Peak Areas
  11.5  Spin Coupling
    11.5.1  The causes of spin coupling
    11.5.2  Coupling constant (J)
    11.5.3  The law of coupling and splitting
    11.5.4  Spectrum analysis
  11.6  NMR Instrument
  11.7  Carbon Spectrum (13C-NMR)
  Extended reading: Paul Lauterbur
  Problems
Chapter 12  Infrared Spectroscopy
  12.1  Theoretical Background
    12.1.1  Introduction
    12.1.2  Generation conditions of infrared absorption spectra
    12.1.3  Molecular vibration
    12.1.4  Vibrational forms of molecules
  12.2  The Infrared Spectrometer
  12.3  Characteristic Absorption of Functional Groups
    12.3.1  The functional group and fingerprint regions
    12.3.2  Characteristic infrared absorption bands
    12.3.3  The intensity of absorption bands
    12.3.4  The infrared spectra of alkane, haloalkane, alkene, benzene and alcohol
  12.4  Identifying Infrared Spectra
  Extended reading: Kirchhoff and Bunsen on Spectroscopy
  Problems
Chapter 13  Aldehydes and Ketones
  13.1  Structure and Nomenclature of Aldehydes and Ketones
    13.1.1  Structure and bonding of carbonyl group
    13.1.2  Nomenclature of aldehydes and ketones
    13.1.3  Physical properties
  13.2  Preparation of Aldehydes and Ketones
    13.2.1  Oxidation of alcohols (dehydrogenation)
    13.2.2  Oxidation of alkenes (ozonolysis)
    13.2.3  Hydrolysis of gem-dihalides
    13.2.4  Hydration of alkynes
    13.2.5  Friedel-Crafts acylation
    13.2.6  Hydroformylation of the linear α-olefins

    13.2.7  Oxidation of side chain of arenes
  13.3  Reactions of Aldehydes and Ketones
    13.3.1  Nucleophilic addition
    13.3.2  The activity of α-hydrogen in aldehydes and ketones
    13.3.3  Oxidation reactions
    13.3.4  Reduction
  13.4  α,β-Unsaturated Carbonyl Compounds
  Extended reading: Organic Chemist Huang Minglong
  Problems
Chapter 14  Carboxylic Acids and Acid Derivatives
  14.1  Nomenclature of Carboxylic Acids and Their Derivatives
    14.1.1  Nomencalture of carboxylic acids
    14.1.2  Nomenclature of carboxylic acid derivatives
  14.2  Structure and Physical Properties of Carboxylic Acids and Their Derivatives
    14.2.1  Structure of carboxylic acids and their derivatives
    14.2.2  Physical properties of carboxylic acids and their derivatives
  14.3  Preparation of Carboxylic Acids
    14.3.1  Oxidation reaction
    14.3.2  Hydrolysis of carboxylic acid derivatives
    14.3.3  Reaction of organometallic compounds with carbon dioxide
    14.3.4  Other methods
  14.4  Acidity of Carboxylic Acids
  14.5  Formation of Acid Halides and Anhydrides
    14.5.1  Formation of acid halides
    14.5.2  Formation of acid anhydrides
  14.6  Hydrolysis of Carboxylic Acid Derivatives
    14.6.1  Hydrolysis reaction
    14.6.2  Hydrolysis reaction mechanism
  14.7  Alcoholysis of Carboxylic Acid Derivatives
    14.7.1  Acylation
    14.7.2  Transesterification
    14.7.3  Esterification reaction mechanism
  14.8  Aminolysis of Carboxylic Acid Derivatives
    14.8.1  Reaction of carboxylic acid derivatives with amines
    14.8.2  Nucleophilic substitution reaction mechanism of amines
  14.9  Reaction of Carboxylic Acid Derivatives with Metal Reagents
    14.9.1  Reaction with metal magnesium reagents
    14.9.2  Reaction with metal lithium reagents
    14.9.3  Reaction with metal copper-lithium reagents
    14.9.4  Reaction with metal cadmium reagents
  14.10  Reductions of Carboxylic Acids and Their Derivatives
    14.10.1  Reduction of carboxylic acids
    14.10.2  Reduction of acid halides
    14.10.3  Reduction of esters
    14.10.4  Reduction of amides
    14.10.5  Reduction of nitriles
  14.11  Other Reactions of Carboxylic Acids and Their Derivatives
    14.11.1  Decarboxylation reaction
    14.11.2  α-Substituted carboxylic acids and their derivatives
    14.11.3  Elimination reaction of esters

    14.11.4  Hoffmann degradation reaction of amides
  14.12  Lactones
  14.13  Lipids and Waxes
  14.14  Carbonic Acid Derivatives
  14.15  Surfactants and Soaps
  Extended reading 1: August Wilhelm von Hofmann
  Extended reading 2: Aspirin (acetylsalicylic acid)
  Problems
Chapter 15  Difunctional Compounds
  15.1  Introduction
  15.2  Hydroxy Aldehydes and Ketones
    15.2.1  Properties
    15.2.2  Preparation
    15.2.3  Reactions
  15.3  Hydroxy Acids
    15.3.1  Properties
    15.3.2  Preparation
    15.3.3  Dehydration of hydroxy acid
  15.4  Dicarboxylic Acids
    15.4.1  Property and reactions
    15.4.2  Acidity of dicarboxylic acids
  15.5  Dicarbonyl Compounds
    15.5.1  Acidity of β-dicarbonyl compounds and stability of enol anion
    15.5.2  Diethyl malonate
    15.5.3  Ethyl acetoacetate
    15.5.4  Michael addition reaction
  15.6  Summary
  Extended reading: Possible Substitutes for White Pollution—Lactic Acid Polymer
  Problems
Chapter 16  Amines and Other Nitrogen-Containing Compounds
  16.1  Amines
    16.1.1  Nomenclature
    16.1.2  Structure and physical properties
    16.1.3  Preparation
    16.1.4  Chemical properties
    16.1.5  Reactions of diazonium ions
  16.2  Nitro Compounds
  16.3  Nitriles
    16.3.1  Nomenclature
    16.3.2  Physical properties
    16.3.3  Preparation
    16.3.4  Reactions of nitriles
  Extended reading: The Development of Nitroglycerin
  Problems
Chapter 17  Heterocyclic Compounds
  17.1  Heterocyclic System
  17.2  Classification and Nomenclature of Heterocycles
  17.3  Structure and Aromaticity of Heterocycles
  17.4  Five-Membered Unsaturated Heterocycles
    17.4.1  Furan

    17.4.2  Thiophene
    17.4.3  Pyrrole
    17.4.4  Indole
  17.5  Six-Membered Unsaturated Heterocycles
  17.6  Quinoline and Isoquinoline
    17.6.1  Quinoline
    17.6.2  Isoquinoline
  Extended reading: Tu Youyou and Artemisinin
  Problems
Chapter 18  Carbohydrates and Nucleic Acids
  18.1  Stereochemistry of Sugars
    18.1.1  The D and L notation
    18.1.2  Configurations of aldoses
    18.1.3  Configurations of ketoses
  18.2  Structure of Glucose
  18.3  Reactions of Monosaccharides
    18.3.1  Reduction
    18.3.2  Oxidation
    18.3.3  Osazone formation
    18.3.4  Ester formation
    18.3.5  Chain elongation
    18.3.6  Chain shortening
  18.4  Disaccharides
  18.5  Polysaccharides
  Extended reading: Hermann Emil Fischer
  Problems
Chapter 19  Amino Acids, Peptides, Proteins and Nucleic Acids
  19.1  Amino Acids
    19.1.1  Nomenclature of amino acids
    19.1.2  Physical properties of amino acids
    19.1.3  The acidity and alkalinity of amino acids
    19.1.4  Amino acid reaction
    19.1.5  Amino acid synthesis
  19.2  Peptides and Proteins
    19.2.1  Peptide nomenclature
    19.2.2  Synthesis of peptides and proteins
    19.2.3  Determination of polypeptide structure
    19.2.4  Protein hierarchy
  19.3  Enzyme
  19.4  Nucleic Acid
  Extended reading: Human Genome Project
  Problems
Chapter 20  Organometallic Compounds
  20.1  Preparation of Organometallic Compounds
    20.1.1  Preparation of organolithium compounds
    20.1.2  Preparation of organomagnesium compounds
    20.1.3  Preparation of organocopper compounds
    20.1.4  Preparation of organozinc compounds
  20.2  Main Reactions of Organometallic Compounds
    20.2.1  Organometallic compounds as Brnsted bases

    20.2.2  Organometallic compounds as nucleophilic reagents
  Extended reading: Karl Ziegler
  Problems
Chapter 21  Orbitals and Organic Chemistry: Pericyclic Reactions
  21.1  Introduction
    21.1.1  Evolution of the theory of concerted reactions
    21.1.2  A review of π molecular orbitals
    21.1.3  Interactions between molecular orbitals
  21.2  Electrocyclic Reaction
  21.3  Cycloaddition Reaction
    21.3.1  Photochemical dimerization of alkenes
    21.3.2  Diels-Alder reaction
  21.4  Sigmatropic Rearrangements
  Extended reading: Robert Burns Woodward
  Problems
Reference

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