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内容大纲
《分析化学实验》(英汉双语版)教材是基于新时期工科创新人才培养需要,根据分析化学实验教学大纲及多年的双语教学实践编写而成的。
全书共分5章,包括分析化学实验基础知识、常用样品制备及分离技术、定量分析基础实验(设置21个实验项目)、综合设计性实验(按化学类、环境类、生物类、制药类、食品类设置31个实验项目)、探索创新实验(设置8个实验项目),共计编入实验项目60个。其中,综合设计性实验旨在培养学生解决实际复杂问题的能力,满足不同专业学生的个性需求;探索创新实验重在激发学生创新意识、培养创造能力、提升科学素养。另外,本书以二维码的形式增加了丰富的数字资源,提供更多学习形式,增加学习趣味性。
本书可作为高等院校化学、化工、材料、环境、生物、食品、制药等相关专业的教材使用,也可供从事化学实验工作的科技人员参考。 -
作者介绍
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目录
Chapter 1 Basic Knowledge of Analytical Chemistry Experiments
1.1 Tasks and Requirements of Analytical Chemistry Experiment
1.2 Laboratory Safety Knowledge
1.3 Basic Knowledge of Quantitative Analysis Experiments
1.4 Instruments and Basic Operations of Quantitative Analysis
1.5 Recording,Processing and Reporting of Experimental Data
Chapter 2 Sample Preparation and Separation Techniques
2.1 Preparation of Samples
2.2 Separation Techniques of Samples
Chapter 3 Basic Experiments for Quantitative Analysis
Experiment 3.1 Analytical Balance Weighing Exercise
Experiment 3.2 Basic Operation for Titration Analysis
Experiment 3.3 Calibration of Volumetric Instruments
Experiment 3.4 Preparation and Standardization of HCl and NaOH Solution
Experiment 3.5 Determination of Total Acidity in Edible Vinegar
Experiment 3.6 Determination of Nitrogen Content in Ammonium Salts—Formaldehyde Method
Experiment 3.7 Determination of Mixed Alkali—Double Indicator Method
Experiment 3.8 Preparation and Standardization of EDTA Solution
Experiment 3.9 Determination of Total Hardness of Tap Water
Experiment 3.10 Determination of Aluminum Content in Industrial Aluminum Sulfate
Experiment 3.11 Determination of Zn2+ and Bi3+ in Mixed Solution by Continuous Titration
Experiment 3.12 Preparation and Standardization of Potassium Permanganate Solution
Experiment 3.13 Determination of H2O2 Content in Hydrogen Peroxide Solution
Experiment 3.14 Determination of Iron in Iron Ore by Potassium Dichromate Method
Experiment 3.15 Preparation and Standardization of Iodine and Sodium Thiosulfate
Experiment 3.16 Determination of Glucose in Glucose Oral Solution
Experiment 3.17 Determination of Copper Content in Copper Alloys
Experiment 3.18 Determination of Chlorine in Tap Water by Mohr Method
Experiment 3.19 Determination of Nickel in Alloy Steel by Dimethylglyoxime Gravimetric Method
Experiment 3.20 Determination of Trace Iron with Phenanthroline by UV-Vis Spectroscopy
Experiment 3.21 Potentiometric Titration of Phosphoric Acid
Chapter 4 Comprehensive Design Experiments
4.1 Chemistry
Experiment 4.1 Determination of Benzoic Acid Content
Experiment 4.2 Determination of Phenol Content
Experiment 4.3 Determination of Purity of Soluble Barium Salt by Gravimetric Method
Experiment 4.4 Determination of Methanol Content in Industrial Alcohol
Experiment 4.5 Determination of Acetic Acid Content by Potentiometric Titration
Experiment 4.6 Determination of Iron,Aluminum,Calcium and Magnesium in Cement Clinker
4.2 Environment
Experiment 4.7 Determination of Total Alkalinity of Water
Experiment 4.8 Determination of Chemica
Experiment 4.16 Determination of Available Phosphorus Content for Compound Fertilizers
Experiment 4.17 Determination of Available Phosphorus in Soil
Experiment 4.18 Macroporous Resin Adsorption and Spectrophotometric Determination of Flavonoids from Gingko Leaves
Experiment 4.19 Determination of Mixed Amino Acids Content
Experiment 4.20 Determination of Reducing Sugar in Tobacco Leaf
4.4 Pharmacy
Experiment 4.21 Determination of NH+4 in Chinese Medicine White Sal-Ammoniac
Experiment 4.22 Determination of Calcium in Calcium Supplement by KMnO4 Method
Experiment 4.23 Determination of Al3+ and Mg2+ in Compound Aluminium Hydroxide Tablets
Experiment 4.24 Determination of the Content of Berberine Hydrochloride
Experiment 4.25 Determination of Acetaminophen in Ankahuangmin Capsules
4.5 Food
Experiment 4.26 Determination of Citric Acid Content in Commercially Available Citrus
Experiment 4.27 Determination of Calcium Content in Calcium Tablets/Milk Powder/Spinach
Experiment 4.28 Determination of NaCl Content in Soy Sauce
Experiment 4.29 Determination of Anthocyanin Content in Blueberries
Experiment 4.30 Determination of Melamine in Milk Products
Experiment 4.31 Determination of Vitamin B12 in Health Foods
Chapter 5 Innovation Experiments
5.1 Chemistry Experiment Competition for College Students
Experiment 5.1 Preparation of Rare Earth Europium(Eu) Complex and Determination of Coordination RatFio
Experiment 5.2 Preparation of Iron Oxide Nanoparticles and Its Application in the Determination of Melamine in Dairy Products
Experiment 5.3 Study on Synthesis of Complex\[Ni(Me3en)(acac)\]BPh4 and Its Solvent/Thermochromic Behavior
Experiment 5.4 Determination of Copper Content in Polynuclear Copper(Ⅰ) Complex
5.2 Research Training Experiments
Experiment 5.5 Gemini Ionic Liquid Modified Graphene Oxide Membranes for ReO-4/TcO-4Adsorption
Experiment 5.6 Colorimetric Determination of Uric Acid with Gold Nanoparticles
Experiment 5.7 A Green Chemistry Technique for Dissolution and Recovery of Gold from Electronic Wastes
Experiment 5.8 Extraction,Content Analysis and Cosmetic Application of Natural Pigment Betacyanin
Appendix
Appendix 1 Concentrations and Densities of Common Acid-Base Solutions
Appendix 2 Common Primary Standard Substances and Their Drying Conditions and Applications
Appendix 3 Preparation of Common Buffer
Appendix 4 Common Indicators
Appendix 5 Dissociation Constants of Weak Acids and Bases
Appendix 6 Stability Constants of Coordination Compounds Formed by Metal Ions and EDTA(18-25℃,I=0.1 mol/L)
Appendix 7 Standard Atomic Weights(1995,IUPAC)
第1章 分析化学实验基础知识
1.1 分析化学实验的任务和要求
1.2 实验室安全知识
1.3 定量
实验3.4 酸碱溶液的配制与标定
实验3.5 食用醋中总酸度的测定
实验3.6 铵盐中氮含量的分析——甲醛法
实验3.7 混合碱的分析——双指示剂法
实验3.8 EDTA溶液的配制与标定
实验3.9 自来水硬度的测定
实验3.10 工业硫酸铝中铝含量的分析
实验3.11 锌铋混合溶液中Zn2+、Bi3+含量的连续测定
实验3.12 高锰酸钾标准溶液的配制与标定
实验3.13 双氧水中过氧化氢含量的测定
实验3.14 铁矿石中铁含量的测定
实验3.15 碘和硫代硫酸钠溶液的配制与标定
实验3.16 葡萄糖口服液中葡萄糖含量的测定
实验3.17 铜合金中铜含量的测定
实验3.18 莫尔法测定自来水中的氯
实验3.19 丁二酮肟重量法测定合金钢中的镍
实验3.20 邻二氮菲分光光度法测定微量铁
实验3.21 磷酸的电位滴定
第4章 综合设计性实验
4.1 化学类
实验4.1 苯甲酸含量的测定
实验4.2 苯酚含量的测定
实验4.3 重量法测定可溶性钡盐的纯度
实验4.4 工业酒精中甲醇含量的测定
实验4.5 电位滴定法测定醋酸含量
实验4.6 水泥熟料中铁、铝、钙、镁含量的测定
4.2 环境类
实验4.7 水质总碱度测定
实验4.8 河水中化学需氧量(COD)的测定
实验4.9 城市污水中硫酸盐含量的测定
实验4.10 分光光度法测定水性涂料中的甲醛
实验4.11 农达中草甘膦含量的测定
4.3 生物类
实验4.12 复合肥料中总氮含量的测定
实验4.13 土壤中有机质含量的测定
实验4.14 复合肥料中氯离子含量的测定
实验4.15 复合肥料中钾含量的测定
实验4.16 复合肥料中有效磷含量的测定
实验4.17 土壤中有效磷的测定
实验4.18 银杏叶总黄酮含量的测定
实验4.19 混合氨基酸的测定
实验4.20 烟叶样品中还原糖的测定
4.4 制药类
实验4.21 中药白硇砂中NH+4含量的测定
实验4.22 高锰酸钾法测定补钙剂中钙含量
实验4.23 复方氢氧化铝片中Al3+和Mg2+含量的测定
实验4.24 盐酸黄连素含量的测定
实验4.25 氨咖黄敏胶囊中对乙酰氨基酚含量的测定
4.5 食品类
实验4.26 市售柑橘中柠檬酸含量的测定
实验4.27 钙片/奶粉/菠菜中钙含量的测定
实验4.28 酱油中NaCl含量的测定
实验4.29 蓝莓中花青素含量的测定
实验4.30 奶制品中三聚氰胺的测定
实验4.31 保健食品中维生素B12的测定
第5章 探索创新实验
5.1 大学生化学竞赛(分析化学部分)
实验5.1 稀土铕配合物的制备及配位比的测定
实验5.2 氧化铁纳米颗粒的制备及用于奶制品中三聚氰胺的测定
实验5.3 配合物\[Ni(Me3en)(acac)\]BPh4的合成及其溶剂/热致变色行为研究
实验5.4 多核铜(Ⅰ)配合物中铜含量的测定
5.2 创新性实验
实验5.5 Gemini离子液体改性氧化石墨烯薄膜在ReO-4/TcO-4吸附中的应用
实验5.6 金纳米粒子比色法检测尿酸
实验5.7 电子废弃物中金元素的绿色溶解与提取
实验5.8 天然色素甜菜红的提取、含量分析及其美妆应用
附录
附录1 常用酸碱的密度、含量和浓度
附录2 常用基准物质的干燥条件和应用
附录3 常见缓冲溶液的配制
附录4 常用酸碱指示剂及配制方法
附录5 弱酸、弱碱的解离常数
附录6 金属离子与EDTA生成配位化合物的稳定常数(18~25℃,I=0.1mol/L)
附录7 原子表(1995,IUPAC)
参考文献
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